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Polarity Workflow

CLI workflow for basal-only three-folded wurtzite polarity.

Command: get-three-folded-wurtzite-polarity

Calculate site polarity from three basal bonds before assigning an apical neighbor.

The three smallest absolute c-axis projections define the basal set and the negative of their signed mean defines delta. Three basal neighbors are sufficient for a complete polarity site. An apical candidate is selected afterward only when it lies on the side required by UP or DOWN polarity. CSV outputs preserve selected and ignored candidates.

Examples


  1. Analyze an AlN slab using formal charges and open z boundaries:
     reaxkit get-three-folded-wurtzite-polarity --center Al --neighbor N --periodic xy --charge-source formal --formal-charge Al=3 N=-3

  2. Plot basal-only delta on an XZ slice:
     reaxkit get-three-folded-wurtzite-polarity --gen-plots --plane xz --slice-range 0 3.2 --plot-value delta

Arguments

Scientific choices

Flag Required Default Help Choices
--center, --cation No Al Choose center species. Example: --center Al Ga, analyzes Al- and Ga-centered sites.
--neighbor, --anion No N Choose neighbor species. Example: --neighbor N, searches nitrogen atoms for basal and apical roles.
--proton No H Choose proton-like species. Example: --proton H, groups sites by nearby hydrogen atoms.
--charge-source No auto Choose dynamic or formal charges. Example: --charge-source formal --formal-charge Al=3 N=-3, calculates charge-weighted values with those charges. auto, reaxff, formal
--formal-charge No Assign species formal charges. Example: --formal-charge Al=3 N=-3 H=1, uses charges in elementary-charge units.
--neighbor-cutoff No 3.0 Set the candidate radius in angstrom. Example: --neighbor-cutoff 2.5, excludes neighbors farther than 2.5 angstrom.
--proton-cutoff No 2.0 Set the proton-proximity radius in angstrom. Example: --proton-cutoff 1.8, marks sites within 1.8 angstrom of H.
--c-axis No 0.0, 0.0, 1.0 Set the Cartesian polar-axis direction. Example: --c-axis 0 0 1, interprets positive z as UP.
--periodic No xyz Choose periodic directions. Example: --periodic xy, wraps candidates across a and b while leaving the surface normal open. none, x, y, z, xy, xz, yz, xyz
--cell-lengths No Override cell lengths in angstrom. Example: --cell-lengths 10 10 16, uses that cell for every frame.
--cell-angles No 90.0, 90.0, 90.0 Set angles for --cell-lengths in degrees. Example: --cell-angles 90 90 120, defines a hexagonal cell.
--frames No Select zero-based source frames. Example: --frames 0:101:10, includes frames 0 through 100 every 10 frames.
--every No 1 Stride the selected frames. Example: --every 5, keeps every fifth selected frame.
--polarity-tolerance No 1e-10 Set the zero-polarity tolerance in angstrom. Example: --polarity-tolerance 1e-6, treats smaller basal means as zero.
--complete-only No False Exclude sites with fewer than three basal neighbors from polarity.csv. Example: --complete-only, retains all valid three-coordinate surface sites.
--plane No Project plots onto a plane; omission gives 3D. Example: --plane xz, plots x horizontally and z vertically. xy, xz, yz
--slice-range No Limit the coordinate omitted by --plane. Example: --plane xz --slice-range 0 3.2, includes sites with y from 0 to 3.2 angstrom.

Input and file selection

Flag Required Default Help Choices
--engine No Select the input adapter. Example: --engine reaxff, bypasses engine auto-detection. reaxff, ams, lammps
--input No . Set the path used for engine detection. Example: --input ./run, inspects ./run.
--run-dir No . Set the fallback simulation directory. Example: --run-dir ./run, resolves default files there.
--fort7 No fort.7 Select the ReaxFF charge file. Example: --fort7 ./run/fort.7, streams charges from that file.
--fort78 No fort.78 Select the applied-field file. Example: --fort78 ./run/fort.78, reads field samples from that file.
--xmolout No xmolout Select the coordinate trajectory. Example: --xmolout ./run/xmolout, reads atom names and positions there.
--summary No Select optional simulation metadata. Example: --summary ./run/summary.txt, reads timing and cell metadata there.

Outputs and plots

Flag Required Default Help Choices
--gen-plots No False Generate one site plot per frame. Example: --gen-plots, writes PNG files under the plots directory.
--plot-value No polarity Choose the plotted site property. Example: --plot-value delta, colors sites by the signed basal-only displacement. polarity, eta, delta, basal, basal-difference
--plot-real-values No False Plot continuous delta values. Example: --plot-real-values, selects the same values as --plot-value delta.
--color-scale No global Choose continuous color normalization. Example: --color-scale frame, rescales colors independently for each frame. global, frame
--view-elevation No 18.0 Set 3D camera elevation in degrees. Example: --view-elevation 25, raises the camera above the xy plane.
--view-azimuth No -60.0 Set 3D camera azimuth in degrees. Example: --view-azimuth 45, rotates the view around z.
--marker-size No 12.0 Set site-marker area. Example: --marker-size 20, draws larger site markers.
--figure-dpi No 180 Set plot resolution. Example: --figure-dpi 300, writes 300-DPI PNG files.
--output-dir No Choose the CSV and plot directory. Example: --output-dir ./three_folded_polarity, writes all analysis artifacts there.
--detail-format No Optional detail format (default: Parquet; legacy: CSV). parquet, csv

Execution

Flag Required Default Help Choices
--execution No auto Execution backend; unsupported backends fall back to serial with a logged reason. auto, serial, threads, processes
--workers No 0 Frame workers: auto or N (default: auto).
--chunk-size No 0 Maximum in-flight frames: auto or N.

Storage and cache

Flag Required Default Help Choices
--run-id No Run identifier for run-scoped layout. Example: --run-id run_91ac0e, which reuses that run identifier.
--project-root No reaxkit_workspace Project root that contains inputs/, data/, analysis/, etc. Example: --project-root ./workspace, which stores run artifacts there.
--analysis-id No Optional analysis artifact id; defaults to run id. Example: --analysis-id comparison-a, which names the analysis artifact explicitly.
--input-cache, --no-input-cache No True Reuse parsed input frames across commands (default: enabled; use --no-input-cache to force source reads for reproducibility checks or benchmarks). Example: --no-input-cache, which reloads frames from their source files.
--frame-cache-max-gb No 10.0 Maximum workspace frame-cache size in GiB (default: 10; use 0 for unlimited). Example: --frame-cache-max-gb 20, which caps cached frames at 20 GiB.
--output-profile No standard Select the shared artifact policy. Standard writes declared default outputs; minimal keeps core tables; full and legacy include optional details. Default: standard. Example: --output-profile full, which includes declared optional detail tables. minimal, standard, full, legacy

Diagnostics and compatibility

Flag Required Default Help Choices
-h, --help No show this help message and exit
--help-all, --all-flags No Show every option, grouped by purpose.
--log No quiet Choose console logging detail. Example: --log verbose, prints diagnostic progress information. verbose, quiet

Common Runtime and Presentation Arguments

These are shared workflow-level CLI flags added before command-specific options, covering runtime context (engine/input/storage) and output presentation/export behavior.

Each command table above includes its shared and inherited options.